Copper catalyzedipso-nitration of iodoarenes, bromoarenes and heterocyclic haloarenes under ligand-free conditions

Publication year: 2012 Source: Tetrahedron Letters, Available online 21 January 2012 P.J. Amal Joseph, S. Priyadarshini, M. Lakshmi Kantam, H. Maheswaran A catalytic protocol for the conversion of haloarenes into the corresponding nitroarenes is presented using copper salts under ligand-free conditions. The method was effectively utilized for theipso-nitration of a broad variety of haloarenes that includes iodoarenes, bromoarenes and heterocyclic haloarenes.

Publication year: 2012 Source: Tetrahedron Letters, Available online 21 January 2012 P.J. Amal Joseph, S. Priyadarshini, M. Lakshmi Kantam, H. Maheswaran A catalytic protocol for the conversion of haloarenes into the corresponding nitroarenes is presented using copper salts under ligand-free conditions. The method was effectively utilized for theipso-nitration of a broad variety of haloarenes that includes iodoarenes, bromoarenes and heterocyclic haloarenes.

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Copper catalyzedipso-nitration of iodoarenes, bromoarenes and heterocyclic haloarenes under ligand-free conditions